| 蒋志武,袁振东,王菲菲.化学通报,2024,87(3):367-373. |
| 硫键：从概念形成到实际应用 |
| The Chalcogen Bond : From Concept Formation to Practical Application |
| 投稿时间：2023-06-01 修订日期：2023-08-13 |
| DOI： |
| 中文关键词: 硫键 硫键的应用 σ-空穴 次级键 分子间作用力 |
| 英文关键词:Germanium element, Germanium isotopes, Scientific method, Scientific thought |
| 基金项目: |
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| 中文摘要: |
| 早期含硫键物质的合成和硫键结构的发现为硫键概念形成奠定了基础。20世纪90年代以来,对硫族原子亲电性和亲核性的探索使人们对硫键的本质有了深刻的认识,促使了硫键概念的形成。此后,化学家分别于2002年和2010年开发了硫键超分子自组装和阴离子识别功能,并开始重视硫键在固体和溶液中的应用。随着新型分子间作用力关注度提高,硫键会越来越受到人们的重视,其应用也会有更广阔的前景。 |
| 英文摘要: |
| The early synthesis of chalcogen bond containing material and the discovery of the structure of chalcogen bond lay the foundation for the formation of the concept of chalcogen bond.Since the 1990s, the exploration of the electrophilic and nucleophilic properties of chalcogen atoms has led to a profound understanding of the nature of sulfur bonds, which has contributed to the formation of the concept of chalcogen bond.Since chemists developed supramolecular self-assembly and anion recognition functions of chalcogen bond in 2002 and 2010 respectively, people began to pay attention to the application of chalcogen bond in solids and solutions.As people pay more attention to the new intermolecular forces, chalcogen bond will be paid more and more attention and its application will have a broader prospect. |
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