| 张书鸣,杨庆.化学通报,2024,87(12):1368-1380. |
| 钴基MOF材料的制备及其在电催化中的应用研究进展 |
| Research progress on the preparation of cobalt-based MOF materials and their application in electrocatalysis |
| 投稿时间：2024-07-19 修订日期：2024-08-26 |
| DOI： |
| 中文关键词: 金属有机框架 钴基材料 电催化 |
| 英文关键词:metal-organic frameworks Cobalt-based materials Electrocatalysis |
| 基金项目:重庆市技术创新与应用发展重点专项(CSTB2023TIAD-KPX0041)、重庆市教委科技项目青年项目(KJQN202301610)、重庆市高等教 育学会高等教育科学研究课题(cqgj23123c)、重庆第二师范学院科研平台建设项目(2021XJPT02)、重庆第二师范学院2024 年大学生科 研项目(KY20240004)、重庆市自然科学基金创新发展联合基金(万州区)(CSTB2024NSCQ-LMX0013)资助 |
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| 中文摘要: |
| 随着全球能源消耗的不断增长和环境污染问题的日益严重,开发清洁、高效、低廉的电催化剂代替价格昂贵的贵金属催化剂已引起研究者们的广泛关注。钴基金属有机框架(MOF)材料具有高活性、良好的电化学稳定性,和较高的电子传导能力,能够有效促进电催化反应的进行,在电催化应用方面表现出可与贵金属催化剂相媲美的性能,逐渐成为化学和材料领域的研究热点。梳理总结目前关于钴基MOF催化剂研究的前沿进展对于设计高效电催化剂具有重要的借鉴意义。本文概述了应用于电催化领域中钴基MOF材料的分类与合成,总结了其在电催化方面的应用,并对钴基MOF材料的发展进行展望,为提高电催化剂的性能研究提供参考。 |
| 英文摘要: |
| With the continuous growth of global energy consumption and the increasingly serious problem of environmental pollution, the development of clean, efficient and inexpensive electrocatalysts to replace expensive precious metal catalysts has attracted extensive attention from researchers. Cobalt-based metal-organic framework (MOF) materials have high activity, good electrochemical stability, and high electron conductivity, which can effectively promote the electrocatalytic reaction, and exhibit performance comparable to that of noble metal catalysts in electrocatalytic applications, and have gradually become a research hotspot in the field of chemistry and materials. It is important to summarize the current research progress on cobalt-based MOF catalysts for the design of high-efficiency electrocatalysts. In this paper, the classification and synthesis of cobalt-based MOF materials used in the field of electrocatalysis are summarized, their applications in electrocatalysis are summarized, and the development of cobalt-based MOF materials is prospected, so as to provide a reference for improving the performance of electrocatalysts. |
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