| 翟佩佩,杜艳青,王惠荣,张晓,梁凤英,额尔敦.化学通报,2025,88(2):192-199. |
| 基于卤素键供体的催化与识别受体研究进展 |
| Advances in catalysis and recognition of receptors based on halogen bond donors |
| 投稿时间：2024-09-09 修订日期：2024-10-17 |
| DOI： |
| 中文关键词: 卤素键 a-空穴 识别 催化 |
| 英文关键词:Halogen bond, a-hole, Recognition, Catalysis |
| 基金项目:国家自然科学基金项目(21961026)、蒙药学一流学科建设-国际合作与交流项目(MYYXTGJ202304)和内蒙古自治区自然科学青年基金项目(2023QN02004)资助 |
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| 中文摘要: |
| 卤素键是指含卤分子实体中,卤原子的亲电区域与同一或另一分子实体中亲核区域的净吸引作用，在药物化学、材料化学、晶体工程等方面发挥着重要作用。卤素键的“?-空穴”具有定向性、可调性、疏水性和供体原子的大小可变等特点，使其在有机催化和超分子化学领域有着广阔的应用前景。本文综述了卤素键在催化和阴离子识别方面的研究进展，并对卤素键的研究方向进行展望，为卤素键在有机催化和分子识别领域的研究提供参考。 |
| 英文摘要: |
| Halogen bonds, defined as the net attractive interaction between the electrophilic region of a halogen atom in one molecule and a nucleophilic region in another molecule or within the same molecule, play a crucial role in fields such as medicinal chemistry, materials science, and crystal engineering. The ?-hole of the halogen bond exhibits directionality, tunability, hydrophobicity, and variability in donor atom size, making it highly promising in areas like organic catalysis and supramolecular chemistry. This article reviews recent advances in the study of halogen bonds in catalysis and anion recognition, and offers perspectives on future research directions. It aims to provide valuable insights for further exploration of halogen bonds in organic catalysis and molecular recognition. |
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