| 张晓彤,孙荣峰,张兴宇,耿文广,黄继凯,孙梓祥.化学通报,2025,88(4):385-391. |
| 非贵金属催化剂在质子交换膜燃料电池氧还原中的研究进展 |
| Research Progress of Non-noble Metal Catalysts in Oxygen Reduction of Proton Exchange Membrane Fuel Cells |
| 投稿时间：2024-12-13 修订日期：2025-01-09 |
| DOI： |
| 中文关键词: 燃料电池 氧还原反应 非贵金属催化剂 碳基催化剂 金属氧化物催化剂 |
| 英文关键词:Fuel cell Oxygen reduction reaction Non-precious metal catalyst Carbon-based catalysts Metal oxide catalysts |
| 基金项目:国家重点研发计划项目(2021YFB4001802-02)、山东省高等学校青年创新团队项目(2022KJ132)和科技型中小企业创新能力提升项目(2022TSGC1222)资助 |
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| 中文摘要: |
| 在质子交换膜燃料电池中，贵金属铂凭借其出色的催化活性在氧还原反应体系中占据关键地位，但其成本高昂，严重阻碍了燃料电池的大规模量产。非贵金属催化剂具备成本低廉、资源丰富以及稳定性较高等优势，成为极具潜力的替代材料。本文基于近年来碳基、金属氧化物以及钙钛矿型结构催化剂的研究进展，分析了催化剂的组成、合成方法和结构设计等对催化性能的影响，包括各催化剂在氧还原反应中的作用机制、优势以及不足等，并指出非贵金属催化剂未来的发展方向，为后续非贵金属催化剂的开发和应用提供参考依据。 |
| 英文摘要: |
| In proton exchange membrane fuel cells, the precious metal platinum occupies a key position in the oxygen reduction reaction system due to its excellent catalytic activity, but its high cost seriously hinders the large-scale mass production of fuel cells. Non-precious metal catalysts have the advantages of low cost, abundant resources and high stability, and have great potential as alternative materials. Based on the research progress of carbon-based, metal oxide and perovskite catalysts in recent years, this paper analyzes the effects of catalyst composition, synthesis method and structure design on the catalytic performance, including the mechanism, advantages and disadvantages of each catalyst in oxygen reduction reaction, and points out the future development direction of non-precious metal catalysts, which provides a reference for the subsequent development and application of non-precious metal catalysts. |
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