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| 光促进十聚钨酸盐/过渡金属协同催化的C-H键官能团化进展 |
| Progress in Photoinduced Decatungstate/Transition Metal-Catalyzed C-H Functionalization |
| 投稿时间：2025-01-08 修订日期：2025-04-26 |
| DOI： |
| 中文关键词: 十聚钨酸盐 过渡金属 光催化 协同催化 C-H键官能团化 |
| 英文关键词:Decatungstate, Transition metal, Photocatalysis, Cooperative catalysis, C-H Functionalization |
| 基金项目:国家自然科学基金项目（81860622），贵州省科技厅基础研究计划项目（ZK[2023]499），贵州省基础研究计划（自然科学）面上项目（黔科合基础MS[2025]051），凯里学院学科专业平台团队一体化建设规划团队项目（YTH-TD20254I）和凯里学院校级科研项目（2025YB016）资助 |
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| 中文摘要: |
| 通过C-H键官能团化将易获得的烷烃/醛底物转化为高价值产物的策略得到了人们的广泛关注。 近年来，光催化领域的快速发展为C-H键活化提供了一种新的方法。其中，光诱导下十聚钨酸盐催化的碳氢键断裂和过渡金属催化的交叉偶联反应的结合已成为C-H键功能化的有力手段。本文对近三年来十聚钨酸盐在光诱导下协同镍、铜、钴催化C-H 键官能团化，构建C-C、C-N以及烯烃双官能团化、烯炔的1,4-二碳官能化等研究进展进行了综述，旨在为光/过渡金属协同催化实现C-H键官能团化研究提供一定参考。 |
| 英文摘要: |
| The conversion of available alkane/aldehyde substrates into high-value compounds via C-H functionalization has attracted widespread attention. In recent years, the rapid development of the field of photocatalysis has provided new methods for C-H bond activation. Among them, the combination of light-induced decapolytungstate-catalyzed C-H bond cleavage and transition metal-catalyzed cross-coupling reactions has emerged as a powerful tool for the functionalization of C-H bonds. Herein, this review summarizes the photoinduced decatungstate/transition metal (nickel, copper, and cobalt)-catalyzed C-H functionalization in the past three years to construct C-C, C-N, olefin bifunctionalization, and 1,4-dicarbon functionalization of enyne, offering some direction for the investigation of functionalization of C-H bonds through photo/transition metal cooperative catalysis. |
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