Ti3C2Tx MXene基材料在DMFC阳极催化剂中的研究进展
Research progress of Ti3C2Tx MXene based materials as anode catalysts in DMFCs
投稿时间:2025-01-22  修订日期:2025-03-13
DOI:
中文关键词:  Ti3C2Tx MXene基材料  甲醇氧化反应  阳极催化剂
英文关键词:Ti3C2Tx MXene-based materials, methanol oxidation reaction, anode catalysts
基金项目:国家自然科学基金项目(22074079)
作者单位邮编
朱国英 湖州市绿色能源材料与电池梯次利用重点实验室智能制造学院湖州学院 313000
姜泽煜 湖州市绿色能源材料与电池梯次利用重点实验室智能制造学院湖州学院 
曹子钊 湖州市绿色能源材料与电池梯次利用重点实验室智能制造学院湖州学院 
梁京卓 湖州市绿色能源材料与电池梯次利用重点实验室智能制造学院湖州学院 
徐慧* 湖州市绿色能源材料与电池梯次利用重点实验室智能制造学院湖州学院 313000
王桦 生命科学学院湖州师范学院 
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中文摘要:
      直接甲醇燃料电池(DMFCs)作为一种可持续的能源转换技术,展现出广阔的应用前景。DMFCs性能优化的核心在于阳极催化剂的设计与改进,旨在高效催化甲醇氧化反应(MOR),从而提升电池的整体性能。然而,甲醇渗透和催化剂效率等问题仍是制约其广泛应用的关键挑战。为解决这些问题,MXene这一新型的二维(2D)材料逐渐受到关注。MXene由过渡金属碳化物、氮化物或碳氮化物构成,该材料具有高强度、高导电性、比表面积高和亲水性等特性。此外MXene表面官能团(-F、-OH)有助于金属粒子锚定活性位点,因此被称为DMFCs的竞争性载体。其中Ti3C2Tx作为MXene的一种,展现出多种显著优势,例如,金属导电性、2D层状结构、小带隙及其功能化表面的亲水性。本文总结了近年来Ti3C2Tx MXene基材料在DMFCs阳极催化剂中的研究进展,并展望其未来发展及应用前景。
英文摘要:
      As a sustainable energy conversion technology, direct methanol fuel cells (DMFCs) have shown broad application prospects. The core of DMFC performance optimization lies in the design and improvement of anode catalysts, aiming to efficiently catalyze the methanol oxidation reaction (MOR) and thereby enhance the overall performance of the battery. However, issues such as methanol permeation and catalyst efficiency remain key challenges that restrict its wide application. To address these problems, MXene, a new type of two-dimensional material, has gradually attracted attention. MXene is composed of transition metal carbides, nitrides, or carbonitrides, and this material features high strength, high electrical conductivity, high specific surface area, and hydrophilicity. Moreover, the surface functional groups (-F, -OH) of MXene facilitate the anchoring of metal particles at active sites, making it a competitive carrier for DMFCs. Among them, Ti3C2Tx, as a type of MXene, exhibits multiple significant advantages, such as metallic conductivity, two-dimensional layered structure, small band gap, and hydrophilicity of its functionalized surface. This article summarizes the research progress of Ti3C2Tx MXene-based materials as anode catalysts in DMFCs in recent years and looks forward to their future development and application prospects.
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