| 陈彦广,张雷,韩洪晶,赵哲吉,韩洪伟,宋华.化学通报,2015,78(7):601. |
| 钙钛矿型混合离子电子导体在能源转化中应用的研究进展 |
| Advances of Perovskite Typed Mixed Ionic and Electronic Conductor in the Process of Energy Conversion and Utilization |
| 投稿时间：2015-01-21 修订日期：2015-03-24 |
| DOI： |
| 中文关键词: 钙钛矿 混合离子电子导体 化学循环燃烧 复合催化剂 |
| 英文关键词:Perovskite mixedionic and electronic conductor chemical looping combustion composite catalyst |
| 基金项目:国家自然科学青年基金，中国博士后科学基金，黑龙江省新世纪优秀人才项目，黑龙江省自然科学青年基金，黑龙江省青年学术骨干支持计划，黑龙江省博士后资助项目 |
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| 中文摘要: |
| 钙钛矿型离子电子导体具有良好的传导氧离子和电子性能,使其在能源转化过程中具有较好的应用前景,已成为人们研究的热点。本文综述了钙钛矿型离子电子导体的主要制备方法,并着重介绍了其在化学循环燃烧、氧气的分离、制备H2、太阳能电池方面的应用。钙钛矿型混合离子电子导体可作为一种复合催化剂,可应用于甲烷选择性氧化工艺,为钙钛矿离子电子导体应用新途径,同时为甲烷高效催化转化利用提供了理论支持。 |
| 英文摘要: |
| Due to the excellent properties for transporting oxygen ions and electrons, perovskite type mixed ionic and electronic conductor (MIEC) has good application prospect in the process of energy conversion and utilization. The preparation methods of perovskite typed mixed ionic and electronic conductor are reviewed, and its applications focusing on chemical looping combustion, oxygen separation, the generation of H2 and the solar cell are summarized. As a kind of composite catalyst, perovskite typed mixed ionic and electronic conductors are used to selectively oxidation of methane, which opens a new way of application for perovskite typed mixed ionic and electronic conductor and provides a theoretical support for efficient catalytic conversion of methane. |
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